This is easy to figure out. Atmosphere is 78% nitrogen. The primary difference in expansion or consistency in pressure really all comes down to moisture content, not the gas.
Dry air is immeasurably different than nitrogen, but air is actually slightly more temperature stable for pressure. Dry air has a gas constant of 286.9, and dry nitrogen 296.8. Water vapor has a gas constant of 461.5
In order of stability:
Dry air 286.9
Dry nitrogen 296.8
Water vapor 461.5
The real worry is how humid the air or nitrogen in the tire is. If there is a great deal of humidity, pressure could be noticeably less stable. My tractor tires are a real problem on hot days, because they are 3/4 full of water for weight.
I fill my race air tank and rear tires with air from a dryer in my shop air system, not that it matters much. The pressure still changes with temperature even with dry air, so I still watch it. I have the dryer for air for radio transmission lines. I bottle my own dry air, instead of buying gas.